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| Names | |||
|---|---|---|---|
| Preferred IUPAC name
3-Aminophenol[2] | |||
| Other names
m-Aminophenol
meta-Aminophenol 3-Hydroxyaniline m-Hydroxyaniline meta-Hydroxyaniline | |||
| Identifiers | |||
3D model (JSmol)
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| 636059 | |||
| ChEBI | |||
| ChEMBL | |||
| ChemSpider | |||
| ECHA InfoCard | 100.008.830 | ||
| EC Number |
| ||
| 2913 | |||
| KEGG | |||
PubChem CID
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| RTECS number |
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| UNII | |||
| UN number | 2512 | ||
CompTox Dashboard (EPA)
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| Properties | |||
| C6H7NO | |||
| Molar mass | 109.128 g·mol−1 | ||
| Appearance | White orthorhombic crystals | ||
| Density | 1.195 g/cm3 | ||
| Melting point | 120 to 124 °C (248 to 255 °F; 393 to 397 K) | ||
| Boiling point | 164 °C (327 °F; 437 K) at 11 mmHg | ||
| Acidity (pKa) |
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| Hazards | |||
| GHS labelling: | |||
 
| |||
| Warning | |||
| H302, H332, H411 | |||
| P261, P264, P270, P271, P273, P301+P312, P304+P312, P304+P340, P312, P330, P391, P501 | |||
| NFPA 704 (fire diamond) | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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3-Aminophenol is an organic compound with formula C6H4(NH2)(OH). It is an aromatic amine and a phenol. It is the meta isomer of 2-aminophenol and 4-aminophenol.
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Transcription
Preparation
3-Aminophenol can be prepared by caustic fusion of 3-aminobenzenesulfonic acid (i.e. heating with NaOH to 245 °C for 6 hours)[4] or from resorcinol via a substitution reaction with ammonium hydroxide.[5]
Uses
One of the most relevant applications of the substance is the synthesis of 3-(diethylamino)phenol, key intermediate for the preparation of several fluorescent dyes (e.g., rhodamine B). Other uses for the compound include hair dye colorants and stabilizers for chlorine-containing thermoplastics.[4]
References
- ^ [https://www.sigmaaldrich.com/US/en/product/aldrich/100242 |ALDRICH&N5=SEARCH_CONCAT_PNO|BRAND_KEY&F=SPEC 3-Aminophenol] at Sigma-Aldrich.
- ^ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 690. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
Only one name is retained, phenol, for C6H5-OH, both as a preferred name and for general nomenclature. The structure is substitutable at any position. Locants 2, 3, and 4 are recommended, not o, m, and p.
- ^ Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. pp. 5–89. ISBN 978-1498754286.
- ^ a b Mitchell, Stephen C.; Waring, Rosemary H. (2000). "Aminophenols". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a02_099. ISBN 9783527303854.
- ^ Harada, Haruhisa; Hiroshi, Maki; Sasaki, Shigeru (1986). "Method for the production of m-aminophenol EP0197633A1". Google Patents. Sumitomo Chemical Company, Limited. Retrieved 3 February 2015.
This page was last edited on 13 January 2024, at 11:25