Thiosulfonates are organosulfur compounds with the formula RSO2SR'. Thiosulfonate esters are produced by oxidation of disulfides or the nucleophilic attack of thiolates on organosulfonyl halides.[1]
Alkali metal thiosulfonates are the conjugate base of thiosulfuric acid. They are prepared by the reaction of organosulfonyl chlorides with sources of sulfide.[1][2]
Oxidation with mCPBA gives disulfones.[1]
YouTube Encyclopedic
-
1/3Views:10 7092 364318
-
Iodine and sodium thiosulfate redox titration calculations | A-Level Chemistry
-
Synthesis of thiols
-
Allyl-S- compounds, capsaicinoids,(Garlic)
Transcription
See also
- Bunte salts are related organosulfur compounds with the formula RSSO3−
- Thiosulfinate a structurally analogous functional group in a lower oxidation state, with the formula RSS(O)R
References
- ^ a b c Zefirov, Nikolai S.; Zyk, Nikolai V.; Beloglazkina, Elena K.; Kutateladze, Andrei G. (1993). "Thiosulfonates: Synthesis, Reactions and Practical Applications". Sulfur Reports. 14: 223–240. doi:10.1080/01961779308055018.
- ^ R. B. Woodward; I. J. Pachter; Monte L. Scheinbaum (1974). "Trimethylene Dithiotosylate And Ethylene Dithiotosylate". Org. Synth. 54: 33. doi:10.15227/orgsyn.054.0033.
 | This organic chemistry article is a stub. You can help Wikipedia by expanding it. |
This page was last edited on 12 March 2024, at 21:32