In organic chemistry, an alicyclic compound contains one or more all-carbon rings which may be either saturated or unsaturated, but do not have aromatic character.[1] Alicyclic compounds may have one or more aliphatic side chains attached.
The simplest alicyclic compounds are the monocyclic cycloalkanes: cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, and so on. Bicyclic alkanes include bicycloundecane, decalin, and housane. Polycyclic alkanes include cubane, basketane, and tetrahedrane.
Spiro compounds have two or more rings that are connected through only one carbon atom.
The mode of ring-closing in the formation of many alicyclic compounds can be predicted by Baldwin's rules.
Otto Wallach, a German chemist, received the 1910 Nobel Prize in Chemistry for his work on alicyclic compounds.[2][3]
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Transcription
Cycloalkenes
Monocyclic cycloalkenes are cyclopropene, cyclobutene, cyclopentene, cyclohexene, cycloheptene, cyclooctene, and so on. Bicyclic alkenes include norbornene and norbornadiene.
Two more examples are shown below, methylenecyclohexane on the left and 1-methylcyclohexene on the right:
Right: regular double bond
An exocyclic group is always shown outside the ring structure, take for instance the exocyclic double bond of the former molecule. Isotoluenes are a prominent class of compounds with exocyclic double bonds.
The placement of double bonds in many alicyclic compounds can be predicted with Bredt's rule.
References
- ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (1995) "Alicyclic compounds". doi:10.1351/goldbook.A00216
- ^ Leopold Ruzicka (1932). "Third Pedler lecture. The life and work of Otto Wallach". J. Chem. Soc.: 1582. doi:10.1039/JR9320001582.
- ^ Christmann, M (2010). "Otto Wallach: Founder of Terpene Chemistry and Nobel Laureate 1910". Angewandte Chemie International Edition. 49 (50): 9580–9586. doi:10.1002/anie.201003155. PMID 21110354.
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This page was last edited on 12 March 2024, at 02:25