Joaquín Álvarez de Toledo y Caro puede referirse a:
- Joaquín Álvarez de Toledo y Caro (1865-1915), XIX duque de Medina Sidonia.
- Joaquín Álvarez de Toledo y Caro (1894-1955), XX duque de Medina Sidonia, hijo del anterior.
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Joaquín Álvarez de Toledo y Caro puede referirse a: