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Zinc azide is a coordination polymer which crystallizes in three polymorphs, all of which feature tetrahedral zinc centers and bridging azide ligands. α-Zn(N3)2 crystallizes in the monoclinic space group and is stable, while the other two polymorphs are metastable. P21/n. β-Zn(N3)2 is trigonal, space group P3221, and γ-Zn(N3)2 is monoclinic, space group C2.
It is easily hydrolyzed, and attempts to prepare it in aqueous solution resulted in the precipitation of basic azides Zn(OH)2−x(N3)x (x = 0.9–1.0). Both the α- and β-forms were found to be very friction- and shock-sensitive, violently exploding in blue flashes, but can be made to decompose slowly by gentle heating, giving off nitrogen gas. In a sealed glass tube with inert atmosphere, this yields zinc nitride, Zn3N2.[1]
References
^ abSchulz, Axel; Villanger, Alexander (2016). "Binary Zinc Azides". Chemistry: A European Journal. 22 (6): 2032–2038. doi:10.1002/chem.201504524. PMID26749253.