Yttrocene

Yttrocene
Identifiers

CAS Number	1294-07-1^Y
3D model (JSmol)	Interactive image
InChI InChI=1S/3C5H5.Y/c31-2-4-5-3-1;/h31-5H;/q3*-1;+3 Key: OLQIFTSPAVIXCQ-UHFFFAOYSA-N
SMILES c1ccc[cH-]1.c2ccc[cH-]2.c3ccc[cH-]3.[Y+3]
Properties
Chemical formula	C₁₅H₁₅Y
Molar mass	284.191 g·mol⁻¹
Melting point	295 °C (568 K)^[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Yttrocene is an organoyttrium compound with the chemical formula Y(C₅H₅)₃. It forms light yellow crystals and can be obtained by reacting anhydrous yttrium(III) chloride and sodium cyclopentadienide in tetrahydrofuran. It decomposes when exposed to water to produce cyclopentadiene and yttrium(III) hydroxide.^[1] Its thermal stability is between ferrocene and other 3D transition metal tricene complexes.^[2]

References

^ ^a ^b G. Wilkinson, J. M. Birmingham (Dec 1954). "CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS". Journal of the American Chemical Society. 76 (23): 6210. doi:10.1021/ja01652a114. ISSN 0002-7863. Archived from the original on 2021-07-16. Retrieved 2020-12-09.
^ "Synthesis and fluorescence of triazoloazines derivatives". Voprosy Khimii i Khimicheskoi Tekhnologii (5): 71–76. Oct 2019. doi:10.32434/0321-4095-2019-126-5-71-76. ISSN 0321-4095.

Yttrium(II)

Yttrium(III)

Organoyttrium(III) compounds	Y(C₅H₅)₃ Y₂(C₂O₄)₃

This page was last edited on 12 May 2024, at 10:58