To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

How to transfigure the Wikipedia

Would you like Wikipedia to always look as professional and up-to-date? We have created a browser extension. It will enhance any encyclopedic page you visit with the magic of the WIKI 2 technology.

Try it — you can delete it anytime.

Install in 5 seconds
4,5
Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
Live Statistics
English Articles
Improved in 24 Hours
Added in 24 Hours
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.
Great Wikipedia has got greater.
.
Leo
Newton
Brights
Milds

Sulfate carbonate

From Wikipedia, the free encyclopedia

Hanksite

The sulfate carbonates are a compound carbonates, or mixed anion compounds that contain sulfate and carbonate ions. Sulfate carbonate minerals are in the 7.DG and 5.BF Nickel-Strunz groupings.[1]

They may be formed by crystallization from a water solution, or by melting a carbonate and sulfate together.

In some structures carbonate and sulfate can substitute for each other. For example a range from 1.4 to 2.2 Na2SO4•Na2CO3 is stable as a solid solution.[2] Silvialite can substitute about half its sulfate with carbonate[3] and the high temperature hexagonal form of sodium sulfate (I) Na2SO4 can substitute unlimited proportions of carbonate instead of sulfate.[4]

Minerals

name formula system space group unit cell volume

Å3

density optical ref
Brianyoungite Zn12(CO3)3(SO4)(OH)16 Monoclinic P21/m a = 15.724 b = 6.256 c = 5.427 β = 90° 533.8 4.09 Biaxial nα = 1.635 nβ = 1.650 [5]
Burkeite Na6(CO3)(SO4)2 orthorhombic a = 7.05 b = 9.21 c = 5.16 335.04 2.57 Biaxial (-) nα = 1.448 nβ = 1.489 nγ = 1.493

2V: measured: 34° , calculated: 32°

Max birefringence: δ = 0.045

[6]
Caledonite Pb5Cu2(SO4)3(CO3)(OH)6 Orthorhombic Pmn21 a = 20.089 b = 7.146 c = 6.56 941.7 5.77 Biaxial (-) nα = 1.818(3) nβ = 1.866(3) nγ = 1.909(3)

2V: measured: 85° , calculated: 84°

Max birefringence: δ = 0.091

bluish green

[7]
Carraraite Ca3(SO4)[Ge(OH)6](CO3) · 12H2O hexagonal P63/m? a = 11.056 c = 10.629 1125.17 Uniaxial (+) nω = 1.479(1) nε = 1.509(1)

Max birefringence: δ = 0.030

[8]
Carbonatecyanotrichite Cu4Al2(CO3,SO4)(OH)12 · 2H2O Orthorhombic Biaxial (+) nα = 1.616 nβ = 1.630 nγ = 1.677

2V: measured: 55° to 60°, calculated: 60°

Max birefringence: δ = 0.061

pale blue

[9]
Claraite (Cu,Zn)15(AsO4)2(CO3)4(SO4)(OH)14·7H2O triclinic P1 a = 10.3343 b = 12.8212 c = 14.7889 α = 113.196°, β = 90.811°, γ = 89.818° 1800.9 [10]
Ferrotychite Na6(Fe,Mn,Mg)2(CO3)4(SO4)[1] Isometric Fd3 a = 13.962 2,721.7 2.79 Isotropic n = 1.550 [11]
Hanksite Na22K(SO4)9(CO3)2Cl hexagonal P 63/m a = 10.4896 c = 21.2415 2024.1 2.562 Uniaxial (-) nω = 1.481 nε = 1.461

Max birefringence: δ = 0.020

[12]
Hauckite Fe3+3(Mg,Mn2+)24Zn18(SO4)4(CO3)2(OH)81 hexagonal P6/mmm a = 9.17 c = 30.21 2200 3.02 Uniaxial (+) nω = 1.630 nε = 1.638

Max birefringence: δ = 0.008

[13]
Jouravskite Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O Hexagonal P63 a = 11.0713 c = 10.6265 Z=3 1128.02 Uniaxial (-) nω = 1.556 nε = 1.540

Max birefringence: δ = 0.016

[14]
Korkinoite Ca4(SO4)2(CO3)2 · 9H2O Orthorhombic Pmmm Biaxial (+) [15]
Latiumite (Ca,K)4(Si,Al)5O11(SO4,CO3) Monoclinic a = 12.06 Å, b = 5.08 Å, c = 10.81 Å

β = 106°

636.6 Biaxial (+/-) nα = 1.600 - 1.603 nβ = 1.606 - 1.609 nγ = 1.614 - 1.615

2V: measured: 83° to 90°, calculated: 84° to 88°

Max Birefringence: δ = 0.014

[16]
Leadhillite Pb4(SO4)(CO3)2(OH)2 Monoclinic P21/b a = 9.11 b = 20.82 c = 11.59

β = 90.46°

2198 6.55 Biaxial (-) nα = 1.870 nβ = 2.009 nγ = 2.010

2V: 10°

Max birefringence: δ = 0.140

[17][18]
Macphersonite Pb4(SO4)(CO3)2(OH)2[17] Orthorhombic a = 10.38 b = 23.05 c = 9.242 2211.8 Biaxial (-) nα = 1.870 nβ = 2.000 nγ = 2.010

2V: measured: 35° calculated: 28°

Max birefringence: δ = 0.140

[19]
Manganotychite Na6(Mn,Fe,Mg)2(SO4)(CO3)4[17] Isometric Fd3 a = 13.9951 2,741.12 2.7 n = 1.544 pink [20]
Mineevite-Y Na25BaY2(SO4)11(HCO3)4(CO3)2F2Cl[17] Hexagonal P63/m a = 8.811 c = 37.03 Z=2 2489.6 Uniaxial (-) nω = 1.536 nε = 1.510

Max birefringence: δ = 0.026

pale green

[21]
Nakauriite Cu8(SO4)4(CO3)(OH)6•48H2O orthorhombic a = 14.58 b = 11.47 c = 16.22 2,712.5 2.39 blue

Biaxial (-) nα = 1.585 nβ = 1.604 nγ = 1.612

2V: measured: 65° , calculated: 64°

Max birefringence: δ = 0.027

[22]
Nasledovite PbMn3Al4(CO3)4(SO4)O5 · 5H2O 3.069 Biaxial [23]
Paraotwayite Ni(OH)2-x(SO4,CO3)0.5x monoclinic a = 7.89 b = 2.96 c = 13.63 β = 91.1° 318 3.30 Biaxial nα = 1.655 nγ = 1.705

Max birefringence: δ = 0.050

emerald-green

[24]
Philolithite Pb12Mn2+(Mg,Mn2+)2(Mn2+,Mg)4(CO3)4(SO4)O6(OH)12Cl4[1] Tetragonal a = 12.627 c = 12.595 2008.2 Biaxial (+) nα = 1.920 nβ = 1.940 nγ = 1.950

Max birefringence: δ = 0.030

apple green

[25]
Putnisite SrCa4Cr83+(CO3)8(SO4)(OH)16·25 H2O Orthorhombic Pnma a = 15.351 b = 20.421 c = 18.270 Z = 4 5727.3 Biaxial(-); α = 1.552 nβ = 1.583 nγ = 1.599

Max birefringence: δ =0.047

violet

[26]
Pyroaurite Mg6Fe2(SO4,CO3)(OH)16·4H2O Trigonal R3_m a = 3.1094 c = 23.4117 196.03 2.1 Uniaxial (-) nω = 1.564 nε = 1.543

Max birefringence: δ = 0.021

[27]
Hexagonal P63/mmc a = 3.113 c = 15.61 131.01
Rapidcreekite Ca2(SO4)(CO3)•4H2O orthorhombic a = 15.49 b = 19.18 c = 6.15 1827.15 Biaxial (+) nα = 1.516 nβ = 1.518 nγ = 1.531

2V: measured: 45° , calculated: 44°

Max birefringence: δ = 0.015

[28]
Schröckingerite NaCa3(UO2)(SO4)(CO3)3F•10(H2O)[17] triclinic P1 a = 9.634 b = 9.635 c = 14.391

α = 91.41(1)°, β = 92.33(1)°, γ = 120.26(1)°

Biaxial (-) nα = 1.495 nβ = 1.543 nγ = 1.544

Max birefringence: δ = 0.049

[29]
Susannite Pb4(SO4)(CO3)2(OH)2[1] trigonal P3 a = 9.07 Å, c = 11.57 Å Z=3 824.62 6.52 clear [30]
Tatarskite Ca6Mg2(SO4)2(CO3)2(OH)4Cl4•7H2O[31] Orthorhombic 2.341 nα = 1.567(2) nβ = 1.654(2) nγ = 1.722 biaxial(-) 2V=83 [32]
Thaumasite Ca3(SO4)[Si(OH)6](CO3) · 12H2O hexagonal P63 a = 11.030 c = 10.396 1095.3 Uniaxial (-) nω = 1.507 nε = 1.468

Max birefringence: δ = 0.039

[33]
Tychite Na6Mg2(SO4)(CO3)4 Isometric Fd3 a = 13.9038 Z=8 2687.82 2.456 isotropic [34]
Alloriite Na19K6Ca5[Al22Si26O96](SO4)5Cl(CO3)x(H2O) trigonal P31c a = 12.892 c = 21.340 [35]
Potassium-Schröckingerite KCa3(UO2)(CO3)3(SO4)F•10H2O triclinic Yellow [36]

Artificial

name formula formula weight crystal system space group unit cell volume density refractive index comment CAS reference
Na4CO3SO4 Hexagonal P3m1 a=5.2284 c=6.8808 Z=1 2.538 uniaxial (-) n=~1.45 [37][38]
Mg4(OH)2(CO3)2SO4·6H2O [39]
LDH-SO4-CO3 Mg6Al2SO4CO3(OH)14·4H2O P3m a=3.070 c=22.3 layered [40]
Co6Al2SO4CO3(OH)14·4H2O [40]
Cu6Al2SO4CO3(OH)14·4H2O [40]
Complexes
Tetrammine carbonatocobalt(III) sulfate trihydrate [Co(NH3)4CO3]2SO4·3H2O Monoclinic P21/c a=7.455 b=10.609 c=23.627 β =98.346 Z=4 1849 1.88 dark red [41]
μ-Carbonato-bis(pentaamminecobalt(III)) sulfate tetrahydrate [Co(NH3)5]2CO3SO4·4H2O dark red 49731-04-6 [42]
μ-Carbonato-μ-dihydroxo-bis(triamminecobalt(III)) sulfate pentahydrate [(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3]SO4 . 5H2O 500.21 Triclinic a= 6.6914 b= 11.2847 c= 11.825, α = 92.766 β= 99.096 γ= 101.496 861.1 1.929 dark red 75476-69-6 [43]

References

  1. ^ a b c d "Susannite: Mineral information, data and localities". www.mindat.org. Retrieved 10 May 2020.
  2. ^ Green, Stanley J.; Frattali, Francis J. (September 1946). "The System Sodium Carbonate-Sodium Sulfate-Sodium Hydroxide-Water at 100°". Journal of the American Chemical Society. 68 (9): 1789–1794. doi:10.1021/ja01213a033.
  3. ^ Teertstra, D. K.; Schindler, M.; Sherriff, B. L.; Hawthorne, F. C. (June 1999). "Silvialite, a new sulfate-dominant member of the scapolite group with an Al-Si composition near the 14/ m – P 4 2 / n phase transition". Mineralogical Magazine. 63 (3): 321–329. Bibcode:1999MinM...63..321T. doi:10.1180/002646199548547. ISSN 0026-461X. S2CID 129588463.
  4. ^ Eysel, W.; Höfer, H. H.; Keester, K. L.; Hahn, Th. (1985-02-01). "Crystal chemistry and structure of Na 2 SO 4 (I) and its solid solutions". Acta Crystallographica Section B: Structural Science. 41 (1): 5–11. Bibcode:1985AcCrB..41....5E. doi:10.1107/S0108768185001501. ISSN 0108-7681.
  5. ^ "Brianyoungite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  6. ^ "Burkeite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  7. ^ "Caledonite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  8. ^ "Carraraite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  9. ^ "Carbonatecyanotrichite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  10. ^ Biagioni, Cristian; Orlandi, Paolo (2017-12-01). "Claraite, (Cu,Zn)15(AsO4)2(CO3)4(SO4)(OH)14·7H2O: redefinition and crystal structure". European Journal of Mineralogy. 29 (6): 1031–1044. Bibcode:2017EJMin..29.1031B. doi:10.1127/ejm/2017/0029-2669. hdl:11568/895507. ISSN 0935-1221.
  11. ^ "Ferrotychite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  12. ^ Callegari, Athos Maria; Boiocchi, Massimo; Zema, Michele; Tarantino, Serena Chiara (2018-08-01). "The crystal structure of hanksite, Na 22 K(CO 3 ) 2 (SO 4 ) 9 Cl, refined from high-resolution X-ray diffraction data". Neues Jahrbuch für Mineralogie - Abhandlungen. 195 (2): 115–122. doi:10.1127/njma/2018/0113. ISSN 0077-7757. S2CID 134964473.
  13. ^ "Hauckite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  14. ^ "Jouravskite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  15. ^ "Korkinoite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  16. ^ "Latiumite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-10.
  17. ^ a b c d e Jones, G. C.; Jackson, B. (2012). Infrared Transmission Spectra of Carbonate Minerals. Springer Science & Business Media. p. 18. ISBN 978-94-011-2120-0.
  18. ^ "Leadhillite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  19. ^ "Macphersonite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  20. ^ "Manganotychite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-05-18.
  21. ^ "Mineevite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  22. ^ "Nakauriite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  23. ^ "Nasledovite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  24. ^ "Paraotwayite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  25. ^ "Philolithite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  26. ^ "Mineralienatlas - Fossilienatlas". www.mineralienatlas.de (in German). Retrieved 2020-06-11.
  27. ^ "Pyroaurite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-10.
  28. ^ "Rapidcreekite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  29. ^ "Schröckingerite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  30. ^ "Susannite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-05-18.
  31. ^ "Tatarskite: Mineral information, data and localities". www.mindat.org. Retrieved 10 May 2020.
  32. ^ "Tatarskite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-05-18.
  33. ^ "Thaumasite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  34. ^ "Tychite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  35. ^ Kaneva, Ekaterina (2015-09-01). "Investigation of the sulfur speciation in cancrinite group minerals using Single crystal X-ray diffraction analysis [in Russian]". {{cite journal}}: Cite journal requires |journal= (help)
  36. ^ "UM1997-27-CO:CaHKSU: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-09.
  37. ^ Swanson, Howard E.; McMurdie, Howard F.; Morris, Marlene C.; Evans, Eloise H.; Paretzkin, Boris (February 1974). "Standard X-ray Diffraction Powder Patterns: Section 11. Data for 70 Substances". UNT Digital Library. p. 51. Retrieved 2020-06-09.
  38. ^ Wang, Jinsheng; Wu, Yinghai; Anthony, Edward J. (July 2007). "Reactions of solid CaSO4 and Na2CO3 and formation of sodium carbonate sulfate double salts". Thermochimica Acta. 459 (1–2): 121–124. doi:10.1016/j.tca.2007.04.014.
  39. ^ Livingstone, A. (September 1987). "A basic magnesium carbonate, a possible dimorph of artinite, from Unst, Shetland". Mineralogical Magazine. 51 (361): 459–462. Bibcode:1987MinM...51..459L. doi:10.1180/minmag.1987.051.361.13. ISSN 0026-461X. S2CID 10869061.
  40. ^ a b c Wu, Jiansong; Yang, Yifeng (October 2019). "Synthesis and Structural Analysis of LDH-SO4-CO3 Whisker". Journal of Wuhan University of Technology-Mater. Sci. Ed. 34 (5): 1085–1088. doi:10.1007/s11595-019-2163-2. ISSN 1000-2413. S2CID 203852725.
  41. ^ Macikenas, Dainius; Hazell, R. G.; Christensen, A. Nørlund; Balashev, Konstantin P.; Songstad, Jon; Mo, Frode; Bartfai, Tamas; Langel, Ülo (1995). "X-Ray Crystallographic Study of Tetrammine-Carbonatocobalt(III) Sulfate Trihydrate, [Co(NH3)4CO3]2SO4.3H2O". Acta Chemica Scandinavica. 49: 636–639. doi:10.3891/acta.chem.scand.49-0636. ISSN 0904-213X.
  42. ^ Kremer, Eduardo; Piriz Mac-Coll, Carlos R. (October 1971). ".mu.-Carbonato-bis(pentaamminecobalt(III)) salts". Inorganic Chemistry. 10 (10): 2182–2186. doi:10.1021/ic50104a018. ISSN 0020-1669.
  43. ^ Churchill, Melvyn Rowen.; Lashewycz, Romana A.; Koshy, Kanayuthu.; Dasgupta, Tara P. (February 1981). "Synthesis, properties, and crystallographic characterization of a dinuclear .mu.-carbonato complex of cobalt(III): [(NH3)3Co(.mu.-OH)2(.mu.-CO3)Co(NH3)3]SO4.5H2O". Inorganic Chemistry. 20 (2): 376–381. doi:10.1021/ic50216a012. ISSN 0020-1669.
This page was last edited on 16 April 2024, at 07:14
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.
Contact WIKI 2
Introduction
Terms of Service
Privacy Policy