Chemical compound
Identifiers
ChemSpider
ECHA InfoCard 100.008.329
EC Number
UNII
UN number
1653
InChI=1S/2CN.Ni/c2*1-2;/q2*-1;+2
Key: NLEUXPOVZGDKJI-UHFFFAOYSA-N
[C-]#N.[C-]#N.[Ni+2]
tetrahydrate: [C-]#N.[C-]#N.O.O.O.O.[Ni+2]
Properties
Ni(CN)2
Molar mass
110.729
Appearance
yellow-brown solid (dry)[1]
Hazards
GHS labelling
Danger
H317 , H334 , H350 , H372 , H410
P201 , P202 , P260 , P261 , P264 , P270 , P272 , P273 , P280 , P281 , P285 , P302+P352 , P304+P341 , P308+P313 , P314 , P321 , P333+P313 , P342+P311 , P363 , P391 , P405 , P501
Related compounds
Iron(II) cyanide Cobalt(II) cyanide
Related compounds
Potassium cyanonickelate
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Nickel dicyanide is the inorganic compound with a chemical formula Ni(CN)2 . It is a gray-green solid that is insoluble in most solvents.[2]
Production Addition of two equivalents of sodium or potassium cyanide to a solution of nickel(II) ions in aqueous solution leads to the precipitation of nickel(II) cyanide tetrahydrate.[3] [2]
Chemical properties K2 [Ni(CN)4 ] (tetracyanonickelate ) solution) Nickel(II) cyanide dissolves in potassium cyanide solution to produce a yellowish solution containing potassium tetracyanonickelate :[2] [3]
Ni(CN)2 + 2 KCN → K2 [Ni(CN)4 ] Nickel(II) cyanide will react with dimethylglyoxime (dmgH2 ) and produce hydrogen cyanide :[4]
Ni(CN)2 + 2 dmgH2 → Ni(dmgH)2 + 2 HCN See also References
^ 《无机化学丛书》.第九卷 锰分族 铁系 铂系. 科学出版社. P286 – "Inorganic Chemistry Series". Volume 9 Manganese Subgroups, Iron Series, Platinum Series. Science Press. P286. Nickel Cyanide (II). 氰化镍(II) – Nickel cyanide(II).
^ a b c Gail, Ernst; Gos, Stephen; Kulzer, Rupprecht; Lorösch, Jürgen; Rubo, Andreas; Sauer, Manfred (2004). Ullmann's Encyclopedia of Industrial Chemistry doi :10.1002/14356007.a08_159.pub2 . ^ a b Fernelius, W. C.; Burbage, Joseph J. (1946). "Potassium Tetracyanonickelate(II)". Inorganic Syntheses . Vol. 2. pp. 227–228. doi :10.1002/9780470132333.ch73 . ISBN 9780470132333 ^ 《无机化学反应方程式手册》.曹忠良 王珍云 编.湖南科学技术出版社.第十三章 铁系元素. – "Handbook of Inorganic Chemical Reaction Equations". Cao Zhongliang, Wang Zhenyun, ed. Hunan Science and Technology Press. Chapter 13: Iron Series Elements. P379 . 【其他含镍的化合物】– 【Other nickel-containing compounds】.
Nickel(0) Nickel(II) Nickel(III) Nickel(IV)
Salts and covalent derivatives of the
cyanide ion
HCN
He
LiCN
<style data-mw-deduplicate="TemplateStyles:r1123817410">'"`UNIQ--templatestyles-0000002B-QINU`"'</style><span class="chemf nowrap">Be(CN)<sub class="template-chem2-sub">2</sub></span>
B(CN)<sub>3</sub>
C(CN)4 C2 (CN)2
NH4 CN ONCN O2 NCN N3 CN OCN− -NCO FCN
Ne
NaCN
Mg(CN)2 Al(CN)3 <link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Si(CN)<sub class="template-chem2-sub">4</sub></span>(CH3 )3 SiCN
P(CN)3 SCN− -NCS (SCN)2 S(CN)2 ClCN
Ar
KCN
Ca(CN)2
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Sc(CN)<sub class="template-chem2-sub">3</sub></span>
Ti
V
Cr(CN)6 3−
Mn
Fe(CN)2 Fe(CN)6 4− Fe(CN)6 3−
Co(CN)2 Ni(CN)2 Ni(CN)4 2− CuCN
Zn(CN)2 Ga(CN)3 <link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Ge(CN)<sub class="template-chem2-sub">2</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">As(CN)<sub class="template-chem2-sub">3</sub></span>(CH3 )2 AsCN (C6 H5 )2 AsCN
SeCN− BrCN
Kr
RbCN
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Sr(CN)<sub class="template-chem2-sub">2</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Y(CN)<sub class="template-chem2-sub">3</sub></span>
Zr
Nb
Mo(CN)8 4−
Tc
Ru
Rh
Pd(CN)2 AgCN
Cd(CN)2 <link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">In(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Sn(CN)<sub class="template-chem2-sub">2</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Sb(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Te(CN)<sub class="template-chem2-sub">2</sub></span>
ICN
Xe
CsCN
Ba(CN)2 *
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Lu(CN)<sub class="template-chem2-sub">3</sub></span>
Hf
Ta
W(CN)<sub>8</sub><sup>4−</sup>
Re
Os
Ir
Pt(CN)4 2- AuCN Au(CN)2 -
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Hg<sub class="template-chem2-sub">2</sub>(CN)<sub class="template-chem2-sub">2</sub></span>Hg(CN)2
TlCN
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Pb(CN)<sub class="template-chem2-sub">2</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Bi(CN)<sub class="template-chem2-sub">3</sub></span>
Po
At
Rn
Fr
Ra
**
Lr
Rf
Db
Sg
Bh
Hs
Mt
Ds
Rg
Cn
Nh
Fl
Mc
Lv
Ts
Og
*
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">La(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Ce(CN)<sub class="template-chem2-sub">3</sub></span>
Pr
Nd
Pm
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Sm(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Eu(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Gd(CN)<sub class="template-chem2-sub">3</sub></span>
Tb
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Dy(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Ho(CN)<sub class="template-chem2-sub">3</sub></span>
Er
Tm
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Yb(CN)<sub class="template-chem2-sub">3</sub></span>
**
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Ac(CN)<sub class="template-chem2-sub">3</sub></span>
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">Th(CN)<sub class="template-chem2-sub">4</sub></span>
Pa
<link href="mw-data:TemplateStyles:r1123817410" rel="mw-deduplicated-inline-style"/><span class="chemf nowrap">UO<sub class="template-chem2-sub">2</sub>(CN)<sub class="template-chem2-sub">2</sub></span>
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No
This page was last edited on 23 September 2023, at 20:59
This page was last edited on 23 September 2023, at 20:59