To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

4,5
Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.
.
Leo
Newton
Brights
Milds

Iodine monochloride

From Wikipedia, the free encyclopedia

Iodine monochloride
I-Cl bond length = 232.07 pm
I-Cl bond length = 232.07 pm
Space-filling model
Space-filling model
A sample of Iodine monochloride reagent
Names
Preferred IUPAC name
Iodine monochloride
Iodine(I) chloride
Systematic IUPAC name
Chloroiodane
Other names
Iodine chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.306 Edit this at Wikidata
EC Number
  • 232-236-7
MeSH Iodine-monochloride
UNII
UN number 1792
  • InChI=1S/ClI/c1-2 checkY
    Key: QZRGKCOWNLSUDK-UHFFFAOYSA-N checkY
  • InChI=1S/ClI/c1-2
    Key: QZRGKCOWNLSUDK-UHFFFAOYSA-N
  • InChI=1/ClI/c1-2
    Key: QZRGKCOWNLSUDK-UHFFFAOYAO
  • ClI
Properties
ICl
Molar mass 162.35 g/mol
Appearance reddish-brown
Density 3.10 g/cm3
Melting point 27.2 °C (81.0 °F; 300.3 K) (α-form)
13.9 °C (β-form)
Boiling point 97.4 °C (207.3 °F; 370.5 K)
Hydrolyzes
Solubility soluble in CS2
acetic acid
pyridine
alcohol, ether, HCl
−54.6×10−6 cm3/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive, reacts with water to release HCl
Safety data sheet (SDS) https://chemicalsafety.com/sds1/sdsviewer.php?id=30683304
Related compounds
Related interhalogen compounds
Chlorine monofluoride
Bromine monochloride
Iodine monobromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Iodine monochloride is an interhalogen compound with the formula ICl. It is a red-brown chemical compound that melts near room temperature. Because of the difference in the electronegativity of iodine and chlorine, this molecule is highly polar and behaves as a source of I+. Discovered in 1814 by Gay-Lussac, iodine monochloride is the first interhalogen compound discovered.[1]

YouTube Encyclopedic

  • 1/3
    Views:
    1 020
    7 291
    10 739
  • Iodine Monochloride Demonstration
  • Esters 8. Finding Iodine Values of Fats & Oils
  • ICl Lewis Structure: How to Draw the Lewis Structure for the Iodine Chloride

Transcription

Preparation

Iodine monochloride is produced simply by combining the halogens in a 1:1 molar ratio, according to the equation

I2 + Cl2 → 2 ICl

When chlorine gas is passed through iodine crystals, one observes the brown vapor of iodine monochloride. Dark brown iodine monochloride liquid is collected. Excess chlorine converts iodine monochloride into iodine trichloride in a reversible reaction:

ICl + Cl2 ⇌ ICl3

Polymorphs

ICl has two polymorphs; α-ICl, which exists as black needles (red by transmitted light) with a melting point of 27.2 °C, and β-ICl, which exists as black platelets (red-brown by transmitted light) with a melting point 13.9 °C.[2]

In the crystal structures of both polymorphs the molecules are arranged in zigzag chains. β-ICl is monoclinic with the space group P21/c.[3]

Reactions and uses

Iodine monochloride is soluble in acids such as HF and HCl but reacts with pure water to form HCl, iodine, and iodic acid:

ICl + H2O → HCl + HI + 12O2
2 ICl + H2O → 2 HCl + I2 + 12O2
5 ICl + 3 H2O → 5 HCl + HIO3 + 2 I2

ICl is a useful reagent in organic synthesis.[2] It is used as a source of electrophilic iodine in the synthesis of certain aromatic iodides.[4] It also cleaves C–Si bonds.

ICl will also add to the double bond in alkenes to give chloro-iodo alkanes.

RCH=CHR′ + ICl → RCH(I)–CH(Cl)R′

When such reactions are conducted in the presence of sodium azide, the iodo-azide RCH(I)–CH(N3)R′ is obtained.[5]

The Wijs solution, iodine monochloride dissolved in acetic acid, is used to determine the iodine value of a substance.

It can also be used to prepare iodates, by reaction with a chlorate. Chlorine is released as a byproduct.

Iodine monochloride is a Lewis acid that forms 1:1 adducts with Lewis bases such as dimethylacetamide and benzene.

References

  1. ^ Greenwood, Norman  N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 790. ISBN 978-0-08-037941-8.
  2. ^ a b Brisbois, R. G.; Wanke, R. A.; Stubbs, K. A.; Stick, R. V. "Iodine Monochloride" Encyclopedia of Reagents for Organic Synthesis, 2004 John Wiley & Sons. doi:10.1002/047084289X.ri014
  3. ^ Carpenter, G. B.; Richards, S. M. (1 April 1962). "The crystal structure of β-iodine monochloride". Acta Crystallographica. 15 (4): 360–364. doi:10.1107/S0365110X62000882.
  4. ^ Wallingford, V. H.; Krüger, P. A. (1943). "5-Iodo-anthranilic Acid". Organic Syntheses.; Collective Volume, vol. 2, p. 349
  5. ^ Padwa, A.; Blacklock, T.; Tremper, A. "3-Phenyl-2H-Azirine-2-carboxaldehyde". Organic Syntheses.; Collective Volume, vol. 6, p. 893
This page was last edited on 4 December 2023, at 07:22
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.