To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

4,5
Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
Live Statistics
English Articles
Improved in 24 Hours
Added in 24 Hours
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.
.
Leo
Newton
Brights
Milds

Hafnium tetrafluoride

From Wikipedia, the free encyclopedia

Hafnium(IV) fluoride
Zirconium(IV) fluoride
Names
IUPAC names
Hafnium(IV) fluoride
Hafnium tetrafluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.856 Edit this at Wikidata
EC Number
  • 237-258-0
  • InChI=1S/4FH.Hf/h4*1H;/q;;;;+4/p-4
    Key: QHEDSQMUHIMDOL-UHFFFAOYSA-J
  • [F-].[F-].[F-].[F-].[Hf+4]
Properties
HfF4
Appearance white crystalline powder
Density 7.1 g/cm3[1]
Boiling point 970 °C (1,780 °F; 1,240 K) (sublimes)[1]
Structure
Monoclinic, mS60[2]
C2/c, No. 15
a = 1.17 nm, b = 0.986 nm, c = 0.764 nm
Hazards
Flash point Non-flammable
Related compounds
Other anions
Hafnium(IV) chloride
Other cations
Titanium(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with 8-coordinate Hf(IV) centers.

Hafnium tetrafluoride forms a trihydrate, which has a polymeric structure consisting of octahedral Hf center, described as (μ−F)2[HfF2(H20)2]n(H2O)n and one water of crystallization. In a rare case where the chemistry of Hf and Zr differ, the trihydrate of zirconium(IV) fluoride has a molecular structure (μ−F)2[ZrF3(H20)3]2, without the lattice water.[3]

References

  1. ^ a b Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.66. ISBN 1-4398-5511-0.
  2. ^ Zachariasen, W. H. (1949). "Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types". Acta Crystallographica. 2 (6): 388–390. doi:10.1107/S0365110X49001016.
  3. ^ Greenwood, Norman  N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 965. ISBN 978-0-08-037941-8.

Further reading

  • Benjamin, S. L., Levason, W., Pugh, D., Reid, G., Zhang, W., "Preparation and structures of coordination complexes of the very hard Lewis acids ZrF4 and HfF4", Dalton Transactions 2012, 41, 12548. doi:10.1039/C2DT31501G
This page was last edited on 11 June 2023, at 16:57
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.