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File:S-(+)-ketamine-hydrochloride-2D-skeletal.png

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Original file(1,833 × 1,900 pixels, file size: 121 KB, MIME type: image/png)

Description

Skeletal formula of (S)-(+)-ketamine hydrochloride, [C13H17ClNO+][Cl].

Based on the conformation in the crystal structure reported in P. Hakey et al., Acta Cryst. E2008, 64, o1487.

Note: The direction of optical rotation in ketamine depends not only on its absolute configuration but also on its conformation, which differs between salts and the free base. This image is based on the crystal structure of the hydrochloride salt form, i.e. (S)-(+)-ketamine, which has an axial phenyl group. In contrast, the free base form of each enantiomer of ketamine exhibits optical rotation in the opposite direction to the corresponding hydrochloride salt and has an equatorial phenyl group. The free bases are thus (R)-(+)-ketamine and (S)-(−)-ketamine.

Image generated in ChemDraw Professional 15.0.
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Author Ben Mills
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Public domain This work has been released into the public domain by its author, Benjah-bmm27. This applies worldwide.

In some countries this may not be legally possible; if so:
Benjah-bmm27 grants anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.

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20 April 2016

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Date/TimeThumbnailDimensionsUserComment
current11:05, 20 April 2016Thumbnail for version as of 11:05, 20 April 20161,833 × 1,900 (121 KB)Benjah-bmm27removing border
11:04, 20 April 2016Thumbnail for version as of 11:04, 20 April 20161,961 × 2,033 (139 KB)Benjah-bmm27<sub></sub>{{Information |Description = Skeletal formula of (''S'')-(+)-ketamine hydrochloride, [C<sub>13</sub>H<sub>17</sub>ClNO<sup>+</sup>][Cl<sup>−</sup>]. Based on the conformation in the crystal structure reported in [http://dx.doi.org/10....
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