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File:Carbenes.svg

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Original file ‎(SVG file, nominally 512 × 197 pixels, file size: 8 KB)

Summary

Description
Carbenes of different electron configurations and geometrical shapes.

Left: Singulet carbene. The central carbon is sp2-configured. Two sp2 orbitals are involved in covalent bonds with the two substituents. Both electrons occupy the third sp2 orbital and the remaining p-orbital is not occupied. This is the typical shape of carbenes with substituents that have a free electron pair adjacent to the central carbon, for instance :CCl2.
Center: Triplet carbene, bent. The central carbon is again sp2-configured, but the two additional electrons occupy both the third sp2 orbital and the remaining p-orbital. This is the typical shape of carbenes with substituents lacking free electron pairs. Examples are :CH2 and :CHPh.

Right: Triplet carbene, straight. The central carbon is sp-configured, resulting in a straight geometry (like in alkynes). The two free electrons occupy the two degenerate p-orbitals. This form is less common than the bent variants.
Date
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Author Hbf878
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I, the copyright holder of this work, hereby publish it under the following license:
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Date/TimeThumbnailDimensionsUserComment
current21:02, 31 August 2019Thumbnail for version as of 21:02, 31 August 2019512 × 197 (8 KB)Hbf878fixed and improved
12:51, 13 December 2017Thumbnail for version as of 12:51, 13 December 2017512 × 188 (10 KB)Hbf878Objects converted to paths, reset canvas size.
12:49, 13 December 2017Thumbnail for version as of 12:49, 13 December 2017129 × 47 (6 KB)Hbf878User created page with UploadWizard
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