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File:Asymmetric Friedel-Crafts alkylation.svg

From Wikipedia, the free encyclopedia

Original file(SVG file, nominally 320 × 147 pixels, file size: 19 KB)

Summary

Description
Asymmetric Friedel-Crafts alkylation example.
Date
Source Own work
Author Krishnavedala
SVG development
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The SVG code is valid.
 
This vector image was created with LaTeX.
Source code
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SVG code

\documentclass[12pt,border=1pt,crop,multi=false,tikz,class=scrartcl]{standalone}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage{chemfig,chemmacros,chemformula}
\usepackage{lmodern}
\usetikzlibrary{decorations.pathmorphing}

\chemsetup[chemformula]{font-shape=sf,format=\sffamily}
\renewcommand*{\familydefault}{\sfdefault}
\renewcommand*\printatom[1]{\ensuremath{\mathsf{#1} } }
\setatomsep{2em}
\setdoublesep{.6ex}
\setarrowdefault{,1,semithick}
\setbondstyle{thick}
%\setarrowlabelsep{1em}

\makeatletter
\begin{document}
\definesubmol\nobond{-[,0.25,,,draw=none]}

%\schemedebug{true}
\schemestart
	\chemfig{*6(-(-N(-[::-60])-[::60])=-=-=-)}
	\arrow{->
		[\scriptsize1.5eq.\hspace{-1.5em}\chemfig{H-[2](=[::60]O)-[::-60](=[::60]O)-[::-60]OEt} \ch{Et2O}, rt.]
		[\scriptsize0.1eq.\hspace{-1em}\chemfig[black!60]{N*5(-(<\ch{"t-Bu"})--O- 
			(-(<[:60])(<:[:120])-[::72]*5(-O--(<:\ch{"t-Bu"})-N=)) =)} \ch{CU(OTf)2}]
	}[,3]
	\chemfig{*6(-(-N(-[::-60])-[::60])=-= (-(-[::60]OH)-[::-60](=[::60]O)-[::-60]OEt) -=-)}
	\hspace{-2em}\parbox{1cm}{\scriptsize78\%\\89\% ee}
\schemestop
\end{document}

Licensing

Public domain This image of a simple structural formula is ineligible for copyright and therefore in the public domain, because it consists entirely of information that is common property and contains no original authorship.

Captions

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Items portrayed in this file

depicts

15 August 2014

image/svg+xml

8251d5c06368be24f3b3aa6645f2592dd5186b87

19,242 byte

147 pixel

320 pixel

File history

Click on a date/time to view the file as it appeared at that time.

Date/TimeThumbnailDimensionsUserComment
current23:55, 12 April 2015Thumbnail for version as of 23:55, 12 April 2015320 × 147 (19 KB)Krishnavedalaincreased arrow length for better clarity
23:52, 12 April 2015Thumbnail for version as of 23:52, 12 April 2015280 × 147 (19 KB)Krishnavedalafixed color of molecule and better rendering
18:59, 15 August 2014Thumbnail for version as of 18:59, 15 August 2014401 × 184 (39 KB)KrishnavedalaUser created page with UploadWizard
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Metadata

Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.