To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
Live Statistics
English Articles
Improved in 24 Hours
Added in 24 Hours
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.

Diffusion pump

From Wikipedia, the free encyclopedia

Six inch oil diffusion pump.
Six inch oil diffusion pump.
Ulvac oil diffusion pump cutaway
Ulvac oil diffusion pump cutaway

Diffusion pumps use a high speed jet of vapor to direct gas molecules in the pump throat down into the bottom of the pump and out the exhaust. They were the first type of high vacuum pumps operating in the regime of free molecular flow, where the movement of the gas molecules can be better understood as diffusion than by conventional fluid dynamics. Invented in 1915 by Wolfgang Gaede, he named it a diffusion pump since his design was based on the finding that gas cannot diffuse against the vapor stream, but will be carried with it to the exhaust.[1] However, the principle of operation might be more precisely described as gas-jet pump, since diffusion plays a role also in other high vacuum pumps. In modern textbooks, the diffusion pump is categorized as a momentum transfer pump.

The diffusion pump is widely used in both industrial and research applications. Most modern diffusion pumps use silicone oil or polyphenyl ethers as the working fluid.


In the late 19th century, most vacuums were creating using a Sprengel pump, which had the advantage of being very simple to operate, and capable of achieving quite good vacuum given enough time. Compared to later pumps, however, the pumping speed was very slow and the vapor pressure of the mercury limited the ultimate vacuum.

Following his invention of the molecular pump, the diffusion pump was invented in 1915 by Wolfgang Gaede,[2] and originally used elemental mercury as the working fluid. After its invention, the design was quickly commercialized by Leybold.[3]

It was then improved by Irving Langmuir and W. Crawford. Cecil Reginald Burch discovered the possibility of using silicone oil in 1928.[4]

Oil diffusion pumps

An oil diffusion pump is used to achieve higher vacuum (lower pressure) than is possible by use of positive displacement pumps alone. Although its use has been mainly associated within the high-vacuum range (down to 10−9 mbar), diffusion pumps today can produce pressures approaching 10−10 mbar when properly used with modern fluids and accessories. The features that make the diffusion pump attractive for high and ultra-high vacuum use are its high pumping speed for all gases and low cost per unit pumping speed when compared with other types of pump used in the same vacuum range. Diffusion pumps cannot discharge directly into the atmosphere, so a mechanical forepump is typically used to maintain an outlet pressure around 0.1 mbar.

Diffusion pumps used on the Calutron mass spectrometers during the Manhattan Project, visible as black cylinders in the upper half of the image
Diffusion pumps used on the Calutron mass spectrometers during the Manhattan Project, visible as black cylinders in the upper half of the image
Diagram of an oil diffusion pump
Diagram of an oil diffusion pump

The oil diffusion pump is operated with an oil of low vapor pressure. The high speed jet is generated by boiling the fluid and directing the vapor through a jet assembly. Note that the oil is gaseous when entering the nozzles. Within the nozzles, the flow changes from laminar to supersonic and molecular. Often, several jets are used in series to enhance the pumping action. The outside of the diffusion pump is cooled using either air flow, water lines or a water-filled jacket. As the vapor jet hits the outer cooled shell of the diffusion pump, the working fluid condenses and is recovered and directed back to the boiler. The pumped gases continue flowing to the base of the pump at increased pressure, flowing out through the diffusion pump outlet, where they are compressed to ambient pressure by the secondary mechanical forepump and exhausted.

Unlike turbomolecular pumps and cryopumps, diffusion pumps have no moving parts and as a result are quite durable and reliable. They can function over pressure ranges of 10−10 to 10−2 mbar. They are driven only by convection and thus have a very low energy efficiency.

One major disadvantage of diffusion pumps is the tendency to backstream oil into the vacuum chamber. This oil can contaminate surfaces inside the chamber or upon contact with hot filaments or electrical discharges may result in carbonaceous or siliceous deposits. Due to backstreaming, oil diffusion pumps are not suitable for use with highly sensitive analytical equipment or other applications which require an extremely clean vacuum environment, but mercury diffusion pumps may be in the case of ultra high vacuum chambers used for metal deposition. Often cold traps and baffles are used to minimize backstreaming, although this results in some loss of pumping speed.

The oil of a diffusion pump cannot be exposed to the atmosphere when hot. If this occurs, the oil will oxidise and has to be replaced, if a fire occurs the smoke and residue may contaminate other parts of the system.

Oil types

The least expensive diffusion pump oils are based on hydrocarbons which have been purified by double-distillation. Compared with the other fluids, they have higher vapor pressure, so are usually limited to a pressure of 1 x 10−6 Torr. They are also the most likely to burn or explode if exposed to oxidizers.

The most common silicone oils used in diffusion pumps are trisiloxanes, which contain the chemical group Si-O-Si-O-Si, to which various phenyl groups or methyl groups are attached. These are available as the so called 702 and 703 blends, which were formerly manufactured by Dow Corning. These can be further separated into 704 and 705 oils, which are made up of the isomers of tetraphenyl tetramethyl trisiloxane and pentaphenyl trimethyl trisiloxane respectively.[5]

For pumping reactive species, usually a polyphenyl ether based oil is used. These oils are the most chemical and heat resistant type of diffusion pump oil.

Steam ejectors

Plot of pumping speed as a function of pressure for a diffusion pump.
Plot of pumping speed as a function of pressure for a diffusion pump.
Early Langmuir mercury diffusion pump (vertical column) and its backing pump (in background), about 1920.  The diffusion pump was widely used in manufacturing vacuum tubes, the key technology which dominated the radio and electronics industry for 50 years.
Early Langmuir mercury diffusion pump (vertical column) and its backing pump (in background), about 1920. The diffusion pump was widely used in manufacturing vacuum tubes, the key technology which dominated the radio and electronics industry for 50 years.

The steam ejector is a popular form of pump for vacuum distillation and freeze-drying. A jet of steam entrains the vapour that must be removed from the vacuum chamber. Steam ejectors can have single or multiple stages, with and without condensers in between the stages. While both steam ejectors and diffusion pumps use jets of vapor to entrain gas, they work on fundamentally different principles - steam ejectors rely on viscous flow and mixing to pump gas, whereas diffusion pumps use molecular diffusion. This has several consequences. In diffusion pumps, the inlet pressure can be much lower than the static pressure of jet, whereas in steam ejectors the two pressures are about the same. Also, diffusion pumps are capable of much higher compression ratios, and cannot discharge directly to atmosphere.

See also


  1. ^ D. G. Avery and R. Witty (1947). "Diffusion pumps: a critical discussion of existing theories". Proc. Phys. Soc. 59 (6): 1016–1030. Bibcode:1947PPS....59.1016A. doi:10.1088/0959-5309/59/6/313.
  2. ^ Gaede, W. (1915). "Die Diffusion der Gase durch Quecksilberdampf bei niederen Drucken und die Diffusionsluftpumpe". Annalen der Physik. 46 (3): 357. Bibcode:1915AnP...351..357G. doi:10.1002/andp.19153510304.
  3. ^ Sella, Andrea (2009-04-28). "Classic Kit: Gaede's diffusion pump". Chemistry World. Retrieved 2019-08-03.
  4. ^ C. R. Burch (1928). "Oils, greases and high vacua". Nature. 122 (3080): 729. Bibcode:1928Natur.122..729B. doi:10.1038/122729c0. S2CID 4126707.
  5. ^ "Pump Fluids". A User's Guide to Vacuum Technology. Hoboken, NJ, USA: John Wiley & Sons, Inc. 2004-12-07. pp. 229–246. doi:10.1002/0471467162.ch13. ISBN 978-0-471-46716-8.

External links

Further reading

Hablanian, M. H. (1994) [1983]. Diffusion Pumps : Performance and Operation. AVS Monograph Series (2nd ed.). New York, NY: American Vacuum Society. ISBN 1-56396-384-1.

This page was last edited on 26 December 2020, at 12:51
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.