To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

How to transfigure the Wikipedia

Would you like Wikipedia to always look as professional and up-to-date? We have created a browser extension. It will enhance any encyclopedic page you visit with the magic of the WIKI 2 technology.

Try it — you can delete it anytime.

Install in 5 seconds
4,5
Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
Live Statistics
English Articles
Improved in 24 Hours
Added in 24 Hours
Languages
Recent
Show all languages
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.
Great Wikipedia has got greater.
.
Leo
Newton
Brights
Milds

Dichlorotetrakis(pyridine)rhodium(III) chloride

From Wikipedia, the free encyclopedia

Dichlorotetrakis(pyridine)­rhodium(III) chloride
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 237-929-8
  • InChI=1S/4C5H5N.3ClH.Rh/c4*1-2-4-6-5-3-1;;;;/h4*1-5H;3*1H;/q;;;;;;;+3/p-3
    Key: SIIBZAPGWNBRSK-UHFFFAOYSA-K
  • C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1.[Cl-].[Cl-].[Cl-].[Rh+3]
Properties
C20H20Cl3N4Rh
Molar mass 525.66 g·mol−1
Appearance yellow solid
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dichlorotetrakis(pyridine)rhodium(III) chloride is the chloride salt of the coordination complex with the formula [RhCl2(pyridine)4]+. Various hydrates are known, but all are yellow solids. The tetrahydrate initially crystallizes from water.[1] The tetrahydrate converts to the monohydrate upon vacuum drying at 100 °C.

The hydrates of [RhCl2(pyridine)4]Cl are prepared by heating rhodium trichloride with an excess of pyridine in the presence of a catalytic amount of a reductant.[2]

Related complexes

The molecular complex RhCl3(pyridine)3 is an intermediate in the synthesis of [RhCl2(pyridine)4]Cl.[3]

References

  1. ^ Vasilchenko, D. B.; Baidina, I. A.; Filatov, E. Yu.; Korenev, S. V. (2009). "Structure and thermal properties of RhPy4Cl2]X Complex Salts (X = Cl−, ReO4−, ClO4−)". Journal of Structural Chemistry. 50 (2): 335–342. doi:10.1007/s10947-009-0046-7.
  2. ^ Gillard, R. D.; Wilkinson, G. W. (1967). "trans-Dichlorotetra(pyridine)rhodium(III) Salts". Inorganic Syntheses. 10: 64–67. doi:10.1002/9780470132418.ch11.
  3. ^ Acharya, K. R.; Tavale, S. S.; Guru Row, T. N. (1984). "Structure of mer-Trichlorotris(pyridine)rhodium(III), RhCl3(C5H5N)3". Acta Crystallographica Section C Crystal Structure Communications. 40 (8): 1327–1328. doi:10.1107/S0108270184007848.
This page was last edited on 23 January 2023, at 12:02
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.
Contact WIKI 2
Introduction
Terms of Service
Privacy Policy