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Copper(II) perchlorate

From Wikipedia, the free encyclopedia

Copper(II) perchlorate
Copper(II) perchlorate hexahydrate

Copper(II) perchlorate hexahydrate
Names
IUPAC name
Copper(II) perchlorate
Other names
Cupric perchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.978 Edit this at Wikidata
EC Number
  • 237-391-4
UNII
  • InChI=1S/2ClHO4.Cu/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
    Key: YRNNKGFMTBWUGL-UHFFFAOYSA-L
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Cu+2]
Properties
Cu(ClO4)2
Molar mass 262.447 g/mol (anhydrous)
370.539 g/mol (hexahydrate)
Appearance Blue crystalline hygroscopic solid (hexahydrate)[1]
Odor odorless
Density 2.225 g/cm3 (hexahydrate)
Melting point 82 °C (180 °F; 355 K) (hexahydrate)
Boiling point 120 °C (248 °F; 393 K) (hexahydrate)
146 g/(100 ml) (30°C)
1.505 (hexahydrate)[2]
Hazards
GHS labelling:
GHS03: Oxidizing
GHS07: Exclamation mark
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)[3]
REL (Recommended)
TWA 1 mg/m3 (as Cu)[3]
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)[3]
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Copper(II) perchlorate is an inorganic compound with the chemical formula Cu(ClO4)2. It is a salt of copper and perchloric acid. It is a hygroscopic crystalline blue solid. It is commonly encountered as copper(II) perchlorate hexahydrate, According to X-ray crystallography, the salt is the aquo complex [Cu(H2O)6]2+ together with the weakly coordinating anion ClO4.[4]

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Transcription

Safety

Like any perchlorate, it is a strong oxidizing agent.

References

  1. ^ "Copper perchlorate | Cl2CuO8 | ChemSpider".
  2. ^ "Copper(Ii) Perchlorate Hexahydrate | 10294-46-9".
  3. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Gallucci, J. C.; Gerkin, R. E. (1989). "Structure of copper(II) perchlorate hexahydrate". Acta Crystallogr. C. 45: 1279–1284. doi:10.1107/S0108270189000818.
This page was last edited on 5 November 2023, at 14:07
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