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From Wikipedia, the free encyclopedia

An adulterant is caused by the act of adulteration, a practice of secretly mixing a substance with another. Typical substances that are adulterated include but are not limited to food, cosmetics, pharmaceuticals, fuel, or other chemicals, that compromise the safety or effectiveness of the said substance.

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  • Detection of Adulteration in Milk - Amrita University
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Transcription

Detection of Adulteration in Milk Adulteration in milk considerably reduces the quality of milk. Soap, acid, starch, table sugar and chemicals like formalin are some of the adulterants added to milk. Most of the chemicals used as adulterants are poisonous and can cause health hazards. Here are some tests to find out some of the common adulterants in milk. Materials Required Milk Methylene blue Test tubes Water bath Concentrated HCl Resorcinol Iodine solution Concentrated Sulphuric acid 0.5% Ferric Chloride solution Phenolphthalein indicator Hot water 2% Sodium hydroxide 2% Sodium hypochlorite 5% phenol Procedure Arrange the required materials on the lab table. Detection of Table Sugar in Milk Pour 10 ml of milk into the test tube labelled “Table Sugar” and using a pipette add Concentrated HCl into the tube. This should be done in the Fume Hood. Now shake the test tube gently so that the milk gets precipitated. Weigh 100milli gram of Resorcinol and add this to the precipitated milk. Then shake the test tube well. The colour of the milk solution changes to light brown. Now place the test tube with the test tube holder in a water bath at 1000C for 5 minutes. The colour of the milk solution turns red, which shows the presence of table sugar in milk. If the colour remains the same it denotes the absence of table sugar in milk. Detection of starch Pour 3 ml milk in a test tube labelled “Starch”. Now place the test tube with the test tube holder in a water bath at 100 C. After 5 minutes remove the tube from the water bath and allow it to cool. Using a dropper add 2-3 drops of Iodine solution to the test tube and shake it well. If the colour of the milk solution turns yellow, it indicates the absence of starch. Dark blue colour indicates the presence of starch in milk. Detection of Benzoic Acid and Salicylic acid Pour 5 ml milk from the beaker into the test tube labelled “Acid“. Add few drops of conc. Sulphuric acid into the milk and shake the test tube gently. This should be done in the Fume Hood. You will observe that the milk is getting precipitated. Now, using a dropper add 0.5% ferric chloride solution drop by drop and mix this well. A Buff colour indicates the presence of Benzoic acid. If you observe a violet colour it shows the presence of salicylic acid in the milk. Detection of Soap Pour 10 ml milk into a test tube labelled “Soap”. Then add 10 ml hot water to the milk. Add 1-2 drops of phenolphthalein indicator into the test tube and mix this gently. If the colour turns pink, it indicates the presence of soap in the milk. If the colour remains the same it shows the absence of soap in milk. Detection of Formalin in milk Pour 2 ml milk into a test tube labelled “Formalin”. To this add 2 ml of 90% sulphuric acid containing Ferric Chloride using a glass pipette. This step should be done in the Fume Hood. A purple violet ring formed at the junction indicates the presence of Formalin in the milk. Detection of Ammonium sulphate in milk Pour 1 ml milk into a test tube labelled “Ammonium Sulphate”. Pipette out 500 micro litre of 2% NaOH solution and add this to the test tube. Discard the used tip and insert a new tip. Pipette out 500micro litre of 2% Sodium Hypochlorite and add this to the milk solution. You will notice that the colour has turned light yellow. Insert a fresh tip and add 500micro litre phenol solution and mix this well. The milk solution turns light bluish colour. Keep this test tube in water bath at 100 C for 20 Seconds. After 20 seconds the colour turns deep blue indicating the presence of Ammonium sulphate. If the solution turns pink, it indicates the absence of ammonium sulphate. Detection of Micro-Organisms in milk Pour 10 ml milk from the beaker into the test tube labelled “Micro-Organism”. Add 8-10 drops of methylene blue into the test tube containing milk and mix the contents well. The colour of the milk solution turns blue. Close the test tube using cotton ball and keep it in the incubator for 30 minutes at 37 C. If the blue coloured milk solution turns white immediately, it indicates a larger count of micro-organism in the milk. If the colour remains the same, it indicates the presence of fewer numbers of microorganisms in the sample.

Definition

Adulteration is the a practice of secretly mixing a substance with another.[1]The secretly added substance will not normally be present in any specification or declared substances due to accident or negligence rather than intent, and also for the introduction of unwanted substances after the product has been made. Adulteration, therefore, implies that the adulterant was introduced deliberately in the initial manufacturing process, or sometimes that it was present in the raw materials and should have been removed, but was not.[citation needed]

An adulterant is distinct from, for example, permitted food preservatives. There can be a fine line between adulterant and additive; chicory may be added to coffee to reduce the cost or achieve a desired flavor—this is adulteration if not declared, but may be stated on the label. Chalk was often added to bread flour; this reduces the cost and increases whiteness, but the calcium confers health benefits, and in modern bread, a little chalk may be included as an additive for this reason.[citation needed]

In wartime, adulterants have been added to make foodstuffs "go further" and prevent shortages. The German word ersatz is widely recognised for such practices during World War II. Such adulteration was sometimes deliberately hidden from the population to prevent loss of morale and propaganda reasons. Some goods considered luxurious in the Soviet Bloc such as coffee were adulterated[how?] to make them affordable to the general population.[citation needed]

In food and beverages

"How the microscope reveals adulteration", microscope slide comparing rice starch (left) and arrowroot (right) and a mixture of the two (center), c. 1909

Past and present examples of adulterated food, some dangerous, include:

History

Historically, the use of adulterants has been common; sometimes dangerous substances have been used. In the United Kingdom up to the Victorian era, adulterants were common; for example, cheeses were sometimes colored with lead. Similar adulteration issues were seen in industries in the United States, during the 19th century. There is a dispute over whether these practices declined primarily due to government regulation or to increased public awareness and concern over the practices.[citation needed]

In the early 21st century, cases of dangerous adulteration occurred in the People's Republic of China.[5][6]

In some African countries, it is not uncommon for thieves to break electric transformers to steal transformer oil, which is then sold to the operators of roadside food stalls to be used for deep frying. When used for frying, it is reported that transformer oil lasts much longer than regular cooking oil. The downside of this misuse of the transformer oil is the threat to the health of the consumers, due to the presence of PCBs.[7]

Adulterant use was first investigated in 1820 by the German chemist Frederick Accum, who identified many toxic metal colorings in food and drink. His work antagonized food suppliers, and he was ultimately discredited by a scandal over his alleged mutilation of books in the Royal Institution library. The physician Arthur Hill Hassall conducted extensive studies in the early 1850s, which were published in The Lancet and led to the 1860 Food Adulteration Act and other legislation.[8] John Postgate led a further campaign, leading to another Act of 1875, which forms the basis of the modern legislation and a system of public analysts who test for adulteration.[citation needed]

At the turn of the 20th century, industrialization in the United States led to a rise in adulteration, which inspired some protest. Accounts of adulteration led the New York Evening Post to parody:

Mary had a little lamb,
And when she saw it sicken,
She shipped it off to Packingtown,
And now it's labeled chicken.[9]

However, even in the 18th century, people complained about adulteration in food:

"The bread I eat in London is a deleterious paste, mixed up with chalk, alum and bone ashes, insipid to the taste and destructive to the constitution. The good people are not ignorant of this adulteration; but they prefer it to wholesome bread, because it is whiter than the meal of corn [wheat]. Thus they sacrifice their taste and their health. . . to a most absurd gratification of a misjudged eye; and the miller or the baker is obliged to poison them and their families, in order to live by his profession." – Tobias Smollett, The Expedition of Humphry Clinker (1771)[10]

Incidents

See also

References

  1. ^ "Difference Between Adulteration and Contamination". Compare the Difference Between Similar Terms. 16 July 2014.
  2. ^ The Times, Police, 5 February 1894; pg. 14
  3. ^ Burros, Marian (9 August 2006). "The Customer Wants a Juicy Steak? Just Add Water". The New York Times.
  4. ^ Weise, Elizabeth (24 April 2007). "Food tests promise tough task for FDA". USA Today. Retrieved 29 April 2007.
  5. ^ Wu, Yong-Ning; Zhao, Yun-Feng; Li, Jin-Guang; Melamine Analysis Group (2009). "A Survey on Occurrence of Melamine and Its Analogues in Tainted Infant Formula in China". Biomedical and Environmental Sciences. 22 (2): 95–99. Bibcode:2009BioES..22...95W. doi:10.1016/S0895-3988(09)60028-3. PMID 19618684.
  6. ^ Li, Xiaoman; Zang, Mingwu; Li, Dan; Zhang, Kaihua; Zhang, Zheqi; Wang, Shouwei (2023). "Meat food fraud risk in Chinese markets 2012–2021". npj Science of Food. 7 (12): 12. doi:10.1038/s41538-023-00189-z. PMC 10070328. PMID 37012259.
  7. ^ Thieves fry Kenya's power grid for fast food, Al Jazeera, 28 December 2014
  8. ^ Coley, Noel (1 March 2005). "The fight against food adulteration". Education in Chemistry. Vol. 42, no. 2. Royal Society of Chemistry. pp. 46–49. Retrieved 19 June 2018.
  9. ^ Jeffrey M. Pilcher, Food in World History New York: Routledge, 2006, p. 59
  10. ^ "Weston A.Price: Against the Grain, Section Bread to Feed the Masses". Archived from the original on 20 August 2010. Retrieved 16 March 2011.
  11. ^ "Juiceless baby juice leads to full-length justice|FDA Consumer". Archived from the original on 10 December 2007.
  12. ^ "Conagra Set to Settle Criminal Charges It Increased Weight and Value of Grain". The New York Times. Bloomberg News. 20 March 1997.
  13. ^ Sinha, Kounteya (10 January 2012). "70% of milk in Delhi, country is adulterated". The Times of India. Retrieved 23 February 2014.
  14. ^ Piper, Kelsey (20 September 2023). "Lead poisoning kills millions annually. One country is showing the way forward". Vox.

Further reading

External links

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