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Chadwick A. Tolman

From Wikipedia, the free encyclopedia

Chadwick Alma Tolman (October 1938 – April 6, 2024) was an American chemist. He obtained his B.S. in Chemistry from Massachusetts Institute of Technology. He earned his Ph.D. in Chemistry as a microwave spectroscopist from U.C. Berkeley under the guidance of William Dulaney Gwinn.[1]

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The ancients believed the stars of the night sky were eternal and unchanging. Today we know this is not true. Stars are born, live their lives, and then die. The way a star dies depends largely on its mass. A low mass star ends as a white dwarf. A high mass star becomes a black hole. But in between, a star becomes a neutron star. Stars spend their lives fusing matter together. This process begins with the simplest of atoms: hydrogen. Fusing hydrogen nuclei gives you helium and releases some energy. It’s this energy which causes the stars to shine. If the star is big enough, then it continues to evolve by fusing matter together to make HEAVIER elements: helium, carbon, neon, oxygen… But at some point the star runs out of steam. Fusion stops, stellar evolution comes to an end, and the star dies. Smaller stars end their lives as a WHITE DWARF, a glowing ball of white hot matter which slowly cools down over billions of years. Although fusion has stopped for white dwarfs, they still shine because of their astronomically high temperature. This is the death that awaits our sun. For the really big stars, the end of fusion enables gravity to do some real damage. Unconstrained by fusion, the gravity of the star breaks down particles and squeezes everything together as tightly as nature will allow. The result is a BLACK HOLE. The gravity of a black hole is so strong that anything that gets close enough is sucked inside - including light. The danger zone is called the Schwarzschild radius. In between white dwarfs and black holes are NEUTRON STARS. These stars are made primarily of neutrons which are NEUTRAL particles. Ernest Rutherford predicted the existence of neutrons in 1920, and a dozen years later, they were observed by James Chadwick. You can find neutrons in the nucleus of most atoms. They can also be created in a process called “electron capture.” With enough force, a proton and electron combine to form a neutron and a neutrino. Neutrinos are super fast and elusive, so they just fly off. But the neutron stays behind. This is the key to understanding how neutron stars are made. Imagine you have a dying star about 50% more massive than our sun. The star’s gravity is strong enough to squeeze the electrons and protons together to form neutrons and neutrinos. The neutrinos dart off into space leaving behind a big sphere of neutrons. Gravity continues to squeeze the neutrons together, but eventually hits a wall - the Pauli Exclusion Principle. This says roughly that two particles cannot occupy the same place at the same time. You now have a neutron star! Let’s quantify the transition from white dwarf to neutron star to black hole. Suppose we have a dead star, and an imaginary dial that lets us change its mass. We’ll set the dial to 1 solar mass - the mass of our sun. This produces a white dwarf, a spinning sphere of white hot matter about the size of the Earth. As we increase the mass by turning the dial, gravity gets stronger, the white dwarf gets smaller, and it spins more quickly. Once we turn the dial to 1.39 solar masses, gravity is strong enough to combine electrons and protons to make neutrons and neutrinos. This value on the dial is called the Chandrasekhar limit. The dead star is now a neutron star. It shrinks down to a sphere with a radius of about 10 kilometers, and the spinning can be as fast as hundreds of times per second. If we move the dial further, gravity eventually becomes strong enough to break down the neutrons, and the neutron star collapses into a black hole. This point on the dial is called the Tolman–Oppenheimer–Volkoff limit and while its exact value is not known, it ranges from 1.5 to 3.0 solar masses. If you were to look at the ingredients of a neutron star, it wouldn’t be 100% neutrons. The number one ingredient is definitely neutrons, but there are still some protons and electrons in there, too. Because the rapidly spinning neutron star contains these charged particles, there will be a massive magnetic field. Just like on Earth, the magnetic field doesn’t have to line up with the axis of rotation. Like a stellar lighthouse, the magnetic field sweeps across the sky emitting regular bursts of electromagnetic radiation. Because of this pulsing signal, neutron stars are sometimes called pulsars. Neutron stars, like the neutron, were predicted to exist before they were observed. Almost as soon as the neutron was detected, astronomers Walter Baade and Fritz Zwicky predicted that a supernova could produce neutron stars. And in 1967, a pulsating neutron star was first observed. In the decades since many more have been discovered. The universe is a pretty big place, and so is that subscribe button. I’m not going to tell you to click it, because I’m certain you’ll do the right thing…… The right thing is to click the button.

Biography

Tolman joined DuPont Central Research in 1965.[2] His early work was on late transition metal complexes with phosphorus ligands. The Tolman cone angle and Tolman electronic parameter[3] are named after him. In 1972, he proposed the 16 and 18 electron rule, extending Irving Langmuir's 18-Electron rule to include the many examples of stable 16 electron square planar d8 complexes.[4] Later work focused on the activation of C-H bonds by transition metal complexes[5][6] and free radical oxidation of cyclohexane for the production of adipic acid, an intermediate in the manufacture of nylon.[7][8]

Tolman was instrumental in the founding of the Delaware Science Alliance and took a year's leave of absence from DuPont to serve as Chair of the Coordinating Committee to help make the Alliance self-sustaining.[9] The primary goal of the Science Alliances was to link scientists interested in education to teachers looking for help in the classroom. Programs include an Elementary Science Olympiad, workshops for volunteers and elementary teachers, summer fellowships in local industry for secondary teachers, and classroom visits and demonstrations by industrial scientists.

Upon retirement from DuPont in 1996, Tolman taught at Delaware Technical & Community College and University of Delaware for a year before joining the National Science Foundation as a program officer in the Chemistry Division. That was followed by two years at the National Academy of Science in the Division of Earth and Life Sciences. His work there included studies and major reports on air pollution and air quality management.[10]

Tolman followed and communicated about climate change issues for over 20 years. He wrote a monthly electronic blog, Climate Change News.[11] He helped write the Statement of Conscience on the Threat of Global Warming/Climate Change for the Unitarian Universalist Association which was adopted by their General Assembly in 2006.[12]

Tolman served on a number of advisory committees. He chaired the Energy Committee of the Delaware Chapter of the Sierra Club, and was a member of the Advocacy Committee of the Delaware Nature Society. He was on the Energy Committee of the Delaware League of Women Voters, and the Climate Change Task Force of the U.S. League of Women Voters, where he helped write the Toolkit for Climate Change Action [13] He served on the Greenhouse Gas Reduction Advisory Committee and the Sea Level Rise Advisory Committee of the State of Delaware.

Tolman was presented the Delaware Audubon Conservation Award at the Delaware Audubon Society Annual Meeting on October 9, 2009.[14]

Tolman died in Maris Grove, Pennsylvania, on April 6, 2024, at the age of 85.[15]

References

  1. ^ Thesis: The Microwave Spectrum and Vibration-Rotation Interaction in 1,1-Difluorocyclopentane
  2. ^ "Dr. Chad Tolman". C. A. Tolman. Archived from the original on 2011-08-13. Retrieved 2011-03-21.
  3. ^ Tolman, C. A. (1977). "Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis". Chem. Rev. 77 (3): 313–348. doi:10.1021/cr60307a002.
  4. ^ Tolman, C. A. (1972). "The 16 and 18 electron rule in organometallic chemistry and homogeneous catalysis". Chem. Soc. Rev. 1 (3): 337. doi:10.1039/CS9720100337.
  5. ^ S. D. Ittel, C. A. Tolman, A. D. English, and J. P. Jesson, "The Chemistry of 2-Naphthyl bis[bis(dimethylphosphino)ethane] Hydride Complexes of Fe, Ru, and Os. 2. Cleavage of sp and sp3 C-H, C-O, and C-X Bonds. Coupling of Carbon Dioxide and Acetonitrile," J. Am. Chem. Soc., 100, 7577 (1978).
  6. ^ C. A. Tolman, S. D. Ittel, A. D. English, and J. P. Jesson, "Chemistry of 2-Naphthyl- bis[bis(dimethylphosphino)ethane] Hydride Complexes of Iron, Ruthenium, and Osmium. 3. Cleavage of sp2 C-H Bonds," J. Am. Chem. Soc., 101, 1742 (1979).
  7. ^ Tolman, C. A.; Druliner, J. D.; Nappa, M. J.; Herron, N.; Alkane Oxidation Studies in Du Pont's Central Research Department; in Act. Funct. Alkanes (1989), 303–60, edited by Craig L Hill
  8. ^ Tolman, C. A.; Druliner, J. D.; Krusic, P. J.; Nappa, M. J.; Seidel, W. C.; Williams, I. D.; Ittel, S. D. Catalytic conversion of cyclohexylhydroperoxide to cyclohexanone and cyclohexanol, Journal of Molecular Catalysis (1988), 48(1), 129–48
  9. ^ John W. Collette, Sharon K. Hake, and Robert D. Lipscomb; The Du Pont Honors Workshop: A Successful Industry-School Partnership, Chapter 6, pp 55–65 in Partnerships in Chemical Research and Education; ACS Symposium Series, Vol. 478, ISBN 978-0-8412-2173-4, November 18, 1992
  10. ^ Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program; National Research Council (24 November 1999). Tooele Chemical Agent Disposal Facility: Update on National Research Council Recommendations. National Academies Press. ISBN 978-0-309-06882-6.
  11. ^ "CLIMATE CHANGE NEWS". Retrieved 19 February 2016.
  12. ^ "Threat of Global Warming/Climate Change". UUA.org. Retrieved 19 February 2016.
  13. ^ http://participate.lwv.org/c/9217/t/6398/p/salsa/web/common/public/content?content_item_KEY=3766 - posted on the web in June 2010.
  14. ^ Delaware Audubon Society; Inc. "Delaware Audubon – Conservation Award 2009". Archived from the original on 3 March 2016. Retrieved 19 February 2016. {{cite web}}: |author2= has generic name (help)
  15. ^ "Obituaries in Wilmington, DE | The News Journal". delawareonline.com. The News Journal. Retrieved 14 April 2024.
This page was last edited on 16 June 2024, at 17:05
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