To install click the Add extension button. That's it.

The source code for the WIKI 2 extension is being checked by specialists of the Mozilla Foundation, Google, and Apple. You could also do it yourself at any point in time.

4,5
Kelly Slayton
Congratulations on this excellent venture… what a great idea!
Alexander Grigorievskiy
I use WIKI 2 every day and almost forgot how the original Wikipedia looks like.
What we do. Every page goes through several hundred of perfecting techniques; in live mode. Quite the same Wikipedia. Just better.
.
Leo
Newton
Brights
Milds

Arsenic tribromide

From Wikipedia, the free encyclopedia

Arsenic tribromide
Ball and stick model of arsenic tribromide
Names
Preferred IUPAC name
Arsenic tribromide
Systematic IUPAC name
Tribromoarsane
Other names
Arsenic(III) bromide
Arsenous bromide, Arsenicum Bromatum, Tribromoarsine
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.143 Edit this at Wikidata
EC Number
  • 232-057-4
RTECS number
  • CG1375000
UNII
  • InChI=1S/AsBr3/c2-1(3)4 checkY
    Key: JMBNQWNFNACVCB-UHFFFAOYSA-N checkY
  • InChI=1S/AsBr3/c2-1(3)4
    Key: JMBNQWNFNACVCB-UHFFFAOYSA-N
  • InChI=1/AsBr3/c2-1(3)4
    Key: JMBNQWNFNACVCB-UHFFFAOYAH
  • Br[As](Br)Br
Properties
AsBr3
Molar mass 314.634 g/mol
Appearance white to pale yellow crystalline solid
Density 3.54 g/cm3
Melting point 31.1 °C (88.0 °F; 304.2 K)
Boiling point 221 °C (430 °F; 494 K)
soluble, partial hydrolysis indicated by fumes
-106.0·10−6 cm3/mol
2.3
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
[1910.1018] TWA 0.010 mg/m3[1]
REL (Recommended)
Ca C 0.002 mg/m3 [15-minute][1]
IDLH (Immediate danger)
Ca [5 mg/m3 (as As)][1]
Related compounds
Related compounds
Phosphorus tribromide
arsenic trichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Arsenic tribromide is an inorganic compound with the formula AsBr3, it is a bromide of arsenic. Arsenic is a chemical element that has the symbol As and atomic number 33. This pyramidal molecule is the only known binary arsenic bromide. AsBr3 is noteworthy for its very high refractive index of approximately 2.3. It also has a very high diamagnetic susceptibility.[2] The compound exists as colourless deliquescent crystals that fume in moist air.

YouTube Encyclopedic

  • 1/5
    Views:
    2 801
    9 409
    10 131
    142 669
    41 084
  • AsBr3 (Arsenic tribromide) Molecular Geometry, Bond Angles
  • How to Draw the Lewis Dot Structure for AsBr3: Arsenic tribromide
  • AsBr3 Lewis Structure & Molecular Geometry
  • ARSENICUM BROMATUM ! Homeopathic medicine ARSENICUM BROMATUM ?king of pimples & Diabetes !
  • AP Chemistry: Stoichiometry 1

Transcription

Preparation

Arsenic tribromide can be prepared by the direct bromination of arsenic powder. Alternatively, arsenic(III) oxide can be used as the precursor in the presence of elemental sulfur:

2 As2O3 + 3 S + 6 Br2 → 4 AsBr3 + 3 SO2

Arsenic tribromide is a highly water soluble crystalline arsenic source for uses compatible with bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Arsenic bromide is generally immediately available in most volumes.[3]

It is soluble in hydrocarbons; carbon tetrachloride; very soluble in ether, benzene, chlorinated hydrocarbons, carbon disulfide, oils, and fats.

Bromides of arsenic

AsBr5 is not known, although the corresponding phosphorus compound PBr5 is well characterized. AsBr3 is the parent for a series of hypervalent anionic bromoarsenates including [As2Br8]2−, [As2Br9]3−, and [As3Br12]3−.[4]

Organoarsenic bromides (CH3)2AsBr and (CH3)AsBr2 are formed efficiently by the copper-catalyzed reaction of methyl bromide with hot arsenic metal. This synthesis is similar to the direct process used for the synthesis of methyl chlorosilanes.

Safety

Arsenic tribromide is highly toxic.  It is a carcinogen and a teratogen.

References

  1. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0038". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ CRC handbook of Chemistry and Physics, CRC Press
  3. ^ "Arsenic Tribromide" in Handbook of Preparative Inorganic Chemistry, 2nd ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 597.
  4. ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
This page was last edited on 14 February 2024, at 14:54
Basis of this page is in Wikipedia. Text is available under the CC BY-SA 3.0 Unported License. Non-text media are available under their specified licenses. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc. WIKI 2 is an independent company and has no affiliation with Wikimedia Foundation.