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10-Deacetylbaccatin

From Wikipedia, the free encyclopedia

10-Deacetylbaccatin III
10-Deacetylbaccatin III molecule
Names
IUPAC name
(2aR,4S,4aS,6R,9S,11S,12S,12aR,12bS)-12b-(Acetyloxy)-12-(benzoyloxy)-1,2a,3,4,4a,6,9,10,11,12,12a,12b-dodecahydro-4,6,9,11-tetrahydroxy-4a,8,13,13-tetramethyl-7,11-methano-5H-cyclodeca(3,4)benz(1,2-b)oxet-5-one
Other names
10-Deacetylbaccatin III
10-Deacetylbaccatine III
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.128.614 Edit this at Wikidata
UNII
  • InChI=1S/C29H36O10/c1-14-17(31)12-29(36)24(38-25(35)16-9-7-6-8-10-16)22-27(5,23(34)21(33)20(14)26(29,3)4)18(32)11-19-28(22,13-37-19)39-15(2)30/h6-10,17-19,21-22,24,31-33,36H,11-13H2,1-5H3/t17-,18-,19+,21+,22-,24-,27+,28-,29+/m0/s1 checkY
    Key: YWLXLRUDGLRYDR-ZHPRIASZSA-N checkY
  • CC1=C2C(C(=O)C3(C(CC4C(C3C(C(C2(C)C)(CC1O)O)OC(=O)C5=CC=CC=C5)(CO4)OC(=O)C)O)C)O
Properties
C29H36O10
Molar mass 544.59 g/mol
Appearance colorless solid
Melting point 234 °C (453 °F; 507 K)
insoluble
Solubility soluble in methanol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

10-Deacetylbaccatins are a series of closely related natural organic compounds isolated from the yew tree (Genera Taxus). 10-Deacetylbaccatin III is a precursor to the anti-cancer drug docetaxel (Taxotere).

10-deacetylbaccatin III 10-O-acetyltransferase converts 10-deacetylbaccatin to baccatin III:

acetyl-CoA + 10-deacetylbaccatin III ⇌ CoA + baccatin III

External links

This page was last edited on 2 June 2020, at 13:09
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