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Tripalmitin

From Wikipedia, the free encyclopedia

Tripalmitin
Skeletal formula of tripalmitin
Names
Systematic IUPAC name
Propane-1,2,3-triyl tri(hexadecanoate)
Other names
Palmitin; Glycerol tripalmitate; Glycerin tripalmitate; Glyceryl tripalmitate; Palmitic triglyceride; Tripalmitoyl glycerol
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.008.272 Edit this at Wikidata
EC Number
  • 209-098-1
RTECS number
  • RT4953500
UNII
  • InChI=1S/C51H98O6/c1-4-7-10-13-16-19-22-25-28-31-34-37-40-43-49(52)55-46-48(57-51(54)45-42-39-36-33-30-27-24-21-18-15-12-9-6-3)47-56-50(53)44-41-38-35-32-29-26-23-20-17-14-11-8-5-2/h48H,4-47H2,1-3H3
    Key: PVNIQBQSYATKKL-UHFFFAOYSA-N
  • InChI=1/C51H98O6/c1-4-7-10-13-16-19-22-25-28-31-34-37-40-43-49(52)55-46-48(57-51(54)45-42-39-36-33-30-27-24-21-18-15-12-9-6-3)47-56-50(53)44-41-38-35-32-29-26-23-20-17-14-11-8-5-2/h48H,4-47H2,1-3H3
    Key: PVNIQBQSYATKKL-UHFFFAOYAV
  • O=C(OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC)CCCCCCCCCCCCCCC
Properties
C51H98O6
Molar mass 807.339 g·mol−1
Appearance White powder
Density 0.8752 g/cm3 (70 °C)[1]
Melting point 44.7–67.4 °C (112.5–153.3 °F; 317.8–340.5 K)[2][3]
Boiling point 315 °C (599 °F; 588 K)
at 760 mmHg[1]
Insoluble
Solubility Soluble in EtOH, (C2H5)2O, C6H6, CHCl3[1]
1.4381 (80 °C)[1]
Structure
Triclinic (β-form)[4]
P1 (β-form)[4]
Thermochemistry
1219.4 J/mol·K (β-form, 281.2 K)
1753.1 J/mol·K (338.8 K)[3][5]
1387.4 J/mol·K (liquid)[5]
−2468.7 kJ/mol[5]
−31605.9 kJ/mol[5]
Hazards
GHS labelling:
GHS09: Environmental hazard
Warning
H411
P273, P391, P501
NFPA 704 (fire diamond)
[6]
NFPA 704 four-colored diamondHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
1
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tripalmitin is a triglyceride derived from the fatty acid palmitic acid.

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Transcription

References

  1. ^ a b c d Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
  2. ^ Hong, Jindui (2010). "Solid−Liquid−Gas Equilibrium of the Ternaries Ibuprofen + Myristic Acid + CO2and Ibuprofen + Tripalmitin + CO2". Journal of Chemical & Engineering Data. 55 (1): 297–302. doi:10.1021/je900342a.
  3. ^ a b Charbonnet, G. H.; Singleton, W. S. (1947). "Thermal properties of fats and oils". Journal of the American Oil Chemists' Society. 24 (5): 140. doi:10.1007/BF02643296. S2CID 101805872.
  4. ^ a b Van Langevelde, A.; Van Malssen, K.; Hollander, F.; Peschar, R.; Schenk, H. (1999). "Structure of mono-acid even-numbered β-triacylglycerols". Acta Crystallographica Section B. 55 (Pt 1): 114–122. Bibcode:1999AcCrB..55..114V. doi:10.1107/S0108768198009392. PMID 10927345.
  5. ^ a b c d Tripalmitin in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-06-19)
  6. ^ "MSDS of Trimyristin". fishersci.ca. Fisher Scientific. Retrieved 2014-06-19.


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