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Quantum tunneling of water

From Wikipedia, the free encyclopedia

The quantum tunneling of water occurs when water molecules in nanochannels exhibit quantum tunneling behavior that smears out the positions of the hydrogen atoms into a pair of correlated rings.[1] In that state, the water molecules become delocalized around a ring and assume an unusual double top-like shape. At low temperatures, the phenomenon showcases the quantum motion of water through the separating potential walls, which is forbidden in classical mechanics, but allowed in quantum mechanics.[2]

The quantum tunneling of water occurs under ultraconfinement in rocks, soil and cell walls.[2] The phenomenon is predicted to help scientists better understand the thermodynamic properties and behavior of water in confined environments such as water diffusion, transport in the channels of cell membranes and in carbon nanotubes.

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Transcription

Some of us were taught in high school that the electron orbits around the nucleus like a planet around the sun. However, this description has been understood as a gross mis-representation for the better part of the last century. As it turns out, there is a characteristic uncertainty related to the very small. No one can tell exactly where something is; the best one can do is figure out where something is most likely to be. We can visualize this with something called a probability cloud. Here we see the probability cloud of a proton at the center of a hydrogen atom. The denser regions are where the proton is more likely to be found. However, this uncertainty is not due to an inability of ours to measure the small in an exact manner; it is a fundamental aspect of the world in which we live, and its implications are extraordinary. Let us take for example the phenomenon of tunneling. If we can't tell exactly where something is then it follows that we can't tell exactly where it's been or where it will be. The best we can hope for is where it most probably will be. So there's a small chance that a racket ball thrown repeatedly at a barrier could just tunnel through the barrier, appearing almost magically on the other side. We don't see this often because a racket ball's pretty big and its uncertainty pretty small. But if we deal with matter on the subatomic scale it becomes much more likely. Here our projectile approaches the barrier, we see here its probability cloud, although it's most likely near the center of the cloud we can see that there is a small chance of it being on the other side of the barrier, and so sometimes it is. Tunneling isn't a mathematical trick or an assumption, it's an observable fact. It's made use of commonly in modern electronics and in a real way allows for life on earth. To see why, let us trace the creation of a photon in the sun. The light from the sun that we see reflected off the moon, the light which drives the earth's weather, that provides the energy for life all originates from the process of nuclear fusion in the sun. Two light atomic nuclei collide, forming a new element, and in the process light is released. But these nuclei are both positively charged and so repel each other. Only if they have enough energy can they overcome this potential barrier and fuse. But if you do the math, the nuclei in the sun don't have enough energy. The sun's just not hot enough, non the less, the sun shines, and it does so because of tunneling. Just like our physical barrier, there's a chance that our particle could be on the other side, and so the sun shines.

History

Quantum tunneling in water was reported as early as 1992. At that time it was known that motions can destroy and regenerate the weak hydrogen bond by internal rotations of the substituent water monomers.[3]

On 18 March 2016, it was reported that the hydrogen bond can be broken by quantum tunneling in the water hexamer. Unlike previously reported tunneling motions in water, this involved the concerted breaking of two hydrogen bonds.[4]

On 22 April 2016, the journal Physical Review Letters reported the quantum tunneling of water molecules as demonstrated at the Spallation Neutron Source and Rutherford Appleton Laboratory. First indications of this phenomenon were seen by scientists from Russia and Germany in 2013[5] based on the splitting of terahertz absorption lines of a water molecule captured in five-ångström channels in beryl. Subsequently it was directly observed using neutron scattering and analyzed by ab initio simulations.[6] In a beryl channel, the water molecule can occupy six symmetrical orientations, in agreement with the known crystal structure.[1] A single orientation has the oxygen atom approximately in the center of the channel, with the two hydrogens pointing to the same side toward one of the channel’s six hexagonal faces. Other orientations point to other faces, but are separated from each other by energy barriers of around 50 meV.[1] These barriers, however, do not stop the hydrogens from tunneling among the six orientations and thus split the ground state energy into multiple levels.[1]

References

  1. ^ a b c d Michael Schirber (22 April 2016). "Focus: Water Molecule Spreads Out When Caged". Physics. 9 (43). Retrieved 23 April 2016.
  2. ^ a b Ron Walli. "New state of water molecule discovered". Phys.org. Retrieved 23 April 2016.
  3. ^ N. Pugliano. Vibration-Rotation-Tunneling Dynamics in Small Water Clusters, Lawrence Berkeley Laboratory, November 1992, p. 6
  4. ^ Richardson, Jeremy O.; et al. (18 March 2016). "Concerted hydrogen-bond breaking by quantum tunneling in the water hexamer prism". Science. 351 (6279): 1310–1313. Bibcode:2016Sci...351.1310R. doi:10.1126/science.aae0012. PMID 26989250.
  5. ^ Gorshunov, Boris P.; et al. (29 May 2013). "Quantum Behavior of Water Molecules Confined to Nanocavities in Gemstones". Journal of Physical Chemistry Letters. 4 (12): 2015–2020. doi:10.1021/jz400782j. PMID 26283245. S2CID 19915207.
  6. ^ Kolesnikov, Alexander I.; et al. (22 April 2016). "Quantum Tunneling of Water in Beryl: A New State of the Water Molecule". Physical Review Letters. 116 (16): 167802. Bibcode:2016PhRvL.116p7802K. doi:10.1103/PhysRevLett.116.167802. PMID 27152824.
This page was last edited on 22 May 2023, at 14:29
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